5610-64-0

5610-64-0结构式

常用中文名：酸性黑 52
常用英文名：Palatine Fast Black Wan
CAS号：5610-64-0
分子式：C₆₀H₃₆Cr₂N₉Na₃O₂₁S₃
分子量：1466.150
相关类别：染料及颜料染料皮革染料
发布时间：2018-04-26 08:00:00
更新时间：2024-01-03 12:13:42

中文名	C.I.酸性黑52
英文名	acid black 52
中文别名	中性络合黑 WA 酸性黑 52 永固黑WAN
英文别名	PALATINE FAST BLACK WAN C.I.AcidBlack52 Chromate(3-), bis(3-hydroxy-4-((2-hydroxy-1-naphthalenyl)azo)-7-nitro-1-naphthalenesulfonato(3-))-, disodium hydrogen MFCD00013214 Acid Black 52 PALATINE FAST BLACK WAN,PURE abcolblackwa 1-Naphthalenesulfonic acid, 3,4-dihydro-4-[2-(2-hydroxy-1-naphthalenyl)hydrazinylidene]-7-nitro-3-oxo-, chromium sodium salt, (4E)- (3:2:2) C.I. Acid Black 52 PALATINE FAST BLACK WAN DYE CONTENT: EINECS 227-029-3

分子式	C₆₀H₃₆Cr₂N₉Na₃O₂₁S₃
分子量	1466.150
精确质量	1464.987183
PSA	529.74000
LogP	18.70770
外观性状	黑色粉末
折射率	1.747
储存条件	密封储存，储存于阴凉、干燥的库房。
稳定性	1.常温常压下稳定，避免与强氧化剂接触。 2.遇浓硫酸呈暗蓝色，稀释后生成黑色沉淀，遇浓硝酸呈黄棕色溶液；遇稀氢氧化钠溶液呈紫黑色
计算化学	1、疏水参数计算参考值（XlogP）： 2、氢键供体数量：7 3、氢键受体数量：27 4、可旋转化学键数量：7 5、互变异构体数量：588 6、拓扑分子极性表面积（TPSA）：483 7、重原子数量：97 8、表面电荷：0 9、复杂度：1800 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：0 13、确定化学键立构中心数量：3 14、不确定化学键立构中心数量：0 15、共价键单元数量：7
更多	1. 性状：黑色粉末 2. 密度（g/mL,25℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：0 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,11mmHg）：未确定 7. 折射率(n20/D)：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,20ºC）：未确定 12. 饱和蒸气压（kPa,25ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：溶于水呈红光黑色，可溶于乙醇和溶纤素，微溶于丙酮，不溶于其他有机溶剂.

Name:	Palatine Fast Black Wan Material Safety Data Sheet
Synonym:	C.I. Acid Black 5
CAS:	5610-64-0

Section 1 - Chemical Product MSDS Name:Palatine Fast Black Wan Material Safety Data Sheet
Synonym:C.I. Acid Black 5

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
5610-64-0	C.i. Acid Black 52	ca 100	227-029-3

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Chronic exposure to water insoluble hexavalent chromium compounds has been shown to be associated with lung cancer and gastrointestinal tract tumors.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5610-64-0: United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0 mg/m3 TWA (as Cr) United Kingdom, WEL - STEL: (listed as chromium (vi) compounds): mg/m3 STEL (as Cr) France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME Cr) Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr 0.01 mg/m3 OEL (certain compounds, as Cr) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: black
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C60H36N9O21S3Na3.Cr2
Molecular Weight: 1488.01

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, sodium oxide, chromium dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5610-64-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
C.i. Acid Black 52 - California: carcinogen, initial date 2/27/87 (listed as Chromium (VI) NTP: Known carcinogen (listed as Chromium (VI) compounds).
IARC: Group 1 carcinogen (listed as Chromium (VI) compounds).

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 5610-64-0: 2
Canada
CAS# 5610-64-0 is listed on Canada's DSL List.
CAS# 5610-64-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5610-64-0 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

安全声明 (欧洲)	S24/25
海关编码	29270000

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