428-59-1

• 常用中文名：全氟环氧丙烷
• 常用英文名：Hexafluoropropylene oxide
• CAS号：428-59-1
• 分子式：C₃F₆O
• 分子量：166.022
• 相关类别： 有机原料 烃类化合物及其衍生物 环烃
• 发布时间：2018-07-29 09:39:13
• 更新时间：2024-01-02 11:55:20

• 1、 作为一个重要的含氟中间体，主要用于合成高档的含氟功能化合物

名称

• 中文名: 六氟环氧丙烷
• 英文名: 2,2,3-trifluoro-3-(trifluoromethyl)oxirane
• 中文别名: 全氟环氧丙烷
• 英文别名: perfluoropropylene oxide; hexafluoro-1,2-epoxypropane; hexafluoropropyleneoxide; Propane, 1,2-epoxy-1,1,2,3,3,3-hexafluoro-; EINECS 207-050-4; 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane; trifluoro(trifluoromethyl)oxirane; hexafluoropropene epoxide; UNII:JPY12AP87N; hexafluoropropylene epoxide; Perfluoro-1,2-epoxypropane; 2-(Trifluoromethyl)trifluorooxirane; Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)-; hexafluorocyclopropylene oxide; Perfluoro-1,2-propenoxide; Hexafluoropropylene oxide; Hexafluoropropene oxide; MFCD00005125; Hfpo

物化性质

• 密度: 1.7±0.1 g/cm3
• 沸点: -42.0±0.0 °C at 760 mmHg
• 熔点: -129°C
• 分子式: C₃F₆O
• 分子量: 166.022
• 闪点: -65.5±21.8 °C
• 精确质量: 165.985336
• PSA: 12.53000
• LogP: 2.43
• 外观性状: 无色、无味的气体
• 蒸汽压: 7099.3±0.1 mmHg at 25°C
• 折射率: 1.263
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应

• 计算化学:

  1.疏水参数计算参考值（XlogP）:2.1

  2.氢键供体数量:0

  3.氢键受体数量:7

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积12.5

  7.重原子数量:10

  8.表面电荷:0

  9.复杂度:161

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:1

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：氧化物为无色无味的气体

  2. 密度（g/mL,25℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：-129

  5. 沸点（ºC,常压）：-42

  6. 沸点（ºC, KPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：-66

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,25ºC）：7100

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：20.5

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：2.43

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不溶于水

MSDS

Name: HEXAFLUOROPROPYLENE OXIDE 98% Material Safety Data Sheet Synonym: CAS: 428-59-1 Section 1 - Chemical Product MSDS Name:HEXAFLUOROPROPYLENE OXIDE 98% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 428-59-1 HEXAFLUOROPROPYLENE OXIDE, 98% 98% 207-050-4 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation. Section 4 - FIRST AID MEASURES Eyes: Not available. Skin: Not available. Ingestion: Not available. Inhalation: Not available. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: Not available. Extinguishing Media: Not available. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Not available. Section 7 - HANDLING and STORAGE Handling: Not available. Storage: Not available. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Exposure Limits CAS# 428-59-1: Personal Protective Equipment Eyes: Not available. Skin: Not available. Clothing: Not available. Respirators: Not available. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Not available. Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Not available. Hazardous Decomposition Products: Not available. Hazardous Polymerization: Not available. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 428-59-1 unlisted. LD50/LC50: Not available. Carcinogenicity: HEXAFLUOROPROPYLENE OXIDE, 98% - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 428-59-1: No information available. Canada CAS# 428-59-1 is listed on Canada's NDSL List. CAS# 428-59-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 428-59-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38;R44
• 安全声明 (欧洲): S7-S26-S37/39-S38
• 危险品运输编码: UN 1956 2.2
• WGK德国: 3
• 危险类别: 2.2
• 海关编码: 2910900090

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海关

海关编码	2910900090
中文概述	2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%