41536-44-1

• 常用中文名：2-吗啉基苯酚
• 常用英文名：2-(4-Morpholino)phenol
• CAS号：41536-44-1
• 分子式：C₁₀H₁₃NO₂
• 分子量：179.21600
• 发布时间：2018-07-12 19:14:54
• 更新时间：2024-01-09 10:17:09
• 下载msds

名称

• 中文名: 2-吗啉基苯酚
• 英文名: 2-Morpholinophenol
• 中文别名: 2-(4-吗啉)苯酚
• 英文别名: 2-morpholin-4-ylphenol

物化性质

• 沸点: 130ºC (0.1 torr)
• 熔点: 126ºC
• 分子式: C₁₀H₁₃NO₂
• 分子量: 179.21600
• 闪点: 144.652 °C
• 精确质量: 179.09500
• PSA: 32.70000
• LogP: 1.29380
• 折射率: 1.575
• 储存条件: 2-8°C，干燥，密封

MSDS

Name: 2-Morpholinophenol 97% Material Safety Data Sheet Synonym: N-(2-Hydroxyphenyl)morpholin CAS: 41536-44-1 Section 1 - Chemical Product MSDS Name:2-Morpholinophenol 97% Material Safety Data Sheet Synonym:N-(2-Hydroxyphenyl)morpholin Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 41536-44-1 2-Morpholinophenol 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 41536-44-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white - slight pink Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 130 deg C @0.1mmHg Freezing/Melting Point: 126 - 129 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H13NO2 Molecular Weight: 179 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, acids, bases, acid chlorides, amines. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 41536-44-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Morpholinophenol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 41536-44-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 41536-44-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 41536-44-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36
• 海关编码: 2934999090

合成路线

110-91-8 533-58-4 ~% 41536-44-1

文献：Carpenter, Richard D.; Verkman, Alan S. European Journal of Organic Chemistry, 2011 , # 7 p. 1242 - 1248

110-91-8 108-94-1 ~% 670-80-4 68134-79-2 详细

文献：Carmack, Marvin; Behforouz, Mohammad; Berchtold, Glenn A.; Berkowitz, Samuel M.; Wiesler, Donald; Barone, Ralph Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1305 - 1318

111-44-4 95-55-6 ~% 41536-44-1

文献：Campbell; Reed Industrial and Engineering Chemistry, 1936 , vol. 28, p. 656

上下游产品

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海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%