20666-12-0

• 常用中文名：鲁米诺单钠盐
• 常用英文名：LUMINOL SODIUM SALT
• CAS号：20666-12-0
• 分子式：C₈H₇N₃NaO₂+
• 分子量：200.15
• 相关类别： 染料试剂
• 发布时间：2018-03-01 08:00:00
• 更新时间：2024-01-06 16:45:40
• Luminol(Diogenes reagent)是化学发光试剂,与一定的氧化剂反应时能发出蓝光。

名称

• 中文名: 鲁米诺单钠盐
• 英文名: 3-aminophthalhydrazide monosodium salt
• 中文别名: 3-氨基邻苯二甲酰肼一钠盐; 鲁米诺钠盐
• 英文别名: 5-Amino-2,3-dihydrophthalazine-1,4-dione,sodium salt; Natrium-3-amino-phthalhydrazid; 3-Aminophthalhydrazide,5-Amino-2,3-dihydro-1,4-phthalazinedione; LUMINOL SODIUM SALT HG; 3-Aminophthalhydrazide monosodium salt; 5-Amino-2,3-dihydro-phthalazin-1,4-dion,Natrium-Salz; Tamirite; Luminol sodium salt; 5-amino-2,3-dihydro-phthalazine-1,4-dione,sodium-salt; 3-AMINOPHTHALHYDRAZIDE SODIUM SALT; Galavit; 1,4-Phthalazinedione, 5-amino-2,3-dihydro-, sodium salt (1:1); MFCD00161491; Luminol Mono Sodium Salt; Tamerit; Luminol (sodium salt); 3-AMinophthalhydrazide sodiuM; Sodium 5-amino-4-oxo-3,4-dihydro-1-phthalazinolate; SODIUM LUMINOL

物化性质

• 密度: 1.433g/cm3
• 沸点: 621.9ºC at 760mmHg
• 熔点: 319-320ºC
• 分子式: C₈H₇N₃NaO₂+
• 分子量: 200.15
• 闪点: 329.9ºC
• PSA: 88.84000
• LogP: 0.00890
• 外观性状: 白色到浅绿色 粉末
• 储存条件:

  保持贮藏器密封

  放入紧密的贮藏器内，储存在阴凉，干燥的地方

• 稳定性:

  如果遵照规格使用和储存则不会分解

  避免接触酸，氧化物，还原剂，碱

• 更多:

  1.性状：白色粉末

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：>300

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

生物活性

• 描述: Luminol(Diogenes reagent)是化学发光试剂,与一定的氧化剂反应时能发出蓝光。
• 相关类别:
  信号通路 >> 其他 >> 其他
  染料试剂
  研究领域 >> 其他
• 参考文献:

  [1]. Luminol, wikipedia

MSDS

Name: 5-Amino-2 3-dihydro-1 4-phthalazinedione sodium salt Material Safety Data Sheet Synonym: Luminol sodium salt; 5-Amino-2,3-dihydro-1,4-phthalazinedione, monosodium salt; 3-Aminophthalic acid hydrazide, sodium salt; Tamerit CAS: 20666-12-0 Section 1 - Chemical Product MSDS Name:5-Amino-2 3-dihydro-1 4-phthalazinedione sodium salt Material Safety Data Sheet Synonym:Luminol sodium salt; 5-Amino-2,3-dihydro-1,4-phthalazinedione, monosodium salt; 3-Aminophthalic acid hydrazide, sodium salt; Tamerit Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 20666-12-0 5-Amino-2,3-dihydro-1,4-phthalazinedio 100 unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid. Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 20666-12-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: off-white Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: > 300 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Soluble. Specific Gravity/Density: Not available. Molecular Formula: C8H6N3O2Na Molecular Weight: 199.1 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Dust generation, excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 20666-12-0 unlisted. LD50/LC50: Not available. LD - lethal dose, oral rat >500 mg/kg for Luminol (CAS = 521-31-3). Carcinogenicity: 5-Amino-2,3-dihydro-1,4-phthalazinedione, sodium salt - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NOT REGULATED Hazard Class: UN Number: Packing Group: IMO Shipping Name: NOT REGULATED Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: NOT REGULATED Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 Wear suitable protective clothing. WGK (Water Danger/Protection) CAS# 20666-12-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 20666-12-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 20666-12-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境。

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 3
• 海关编码: 2933990090

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%