175136-61-5

• 常用中文名：6-氯-8-(氯甲基)-4H-4,3-苯并二唑
• 常用英文名：6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine
• CAS号：175136-61-5
• 分子式：C₉H₈Cl₂O₂
• 分子量：219.06500
• 发布时间：2018-12-28 17:27:22
• 更新时间：2024-01-24 10:38:41

名称

• 中文名: 6-氯-8-(氯甲基)-4H-4,3-苯并二唑
• 英文名: 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine
• 中文别名: 6-氯-8-(氯甲基)-4H-苯并[d][1,3]二噁英
• 英文别名: 6-chloro-8-chloromethyl-4H-benzo[1,3]dioxin; 6-CHLORO-8-CHLOROMETHYLBENZO-1,3-DIOXANE; 6-Chlor-8-chlormethyl-4H-benzo[1,3]dioxin; BB_SC-5957

物化性质

• 密度: 1.386g/cm3
• 沸点: 351.5ºC at 760 mmHg
• 熔点: 101ºC
• 分子式: C₉H₈Cl₂O₂
• 分子量: 219.06500
• 闪点: 148.9ºC
• 精确质量: 217.99000
• PSA: 18.46000
• LogP: 2.94530
• 蒸汽压: 8.31E-05mmHg at 25°C
• 折射率: 1.567

MSDS

Name: 6-Chloro-8-(chloromethyl)-4h-1 3-benzodioxine 97% Material Safety Data Sheet Synonym: 6-Chloro-8-chloromethylbenzo-1,3-dioxin CAS: 175136-61-5 Section 1 - Chemical Product MSDS Name:6-Chloro-8-(chloromethyl)-4h-1 3-benzodioxine 97% Material Safety Data Sheet Synonym:6-Chloro-8-chloromethylbenzo-1,3-dioxin Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 175136-61-5 6-Chloro-8-(chloromethyl)-4H-1,3-benzo 97% unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 175136-61-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 99 - 101 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H8Cl2O2 Molecular Weight: 219 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, bases. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 175136-61-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 6-Chloro-8-(chloromethyl)-4H-1,3-benzodioxine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.* Hazard Class: 8 UN Number: 3261 Packing Group: III IMO Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing Group: III RID/ADR Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 175136-61-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 175136-61-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 175136-61-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26
• 海关编码: 2932999099

合成路线

50-00-0 106-48-9 ~% 175136-61-5

文献：Journal of the American Chemical Society, , vol. 62, p. 890,891

50-00-0 2937-59-9 ~% 175136-61-5

文献：Chemische Berichte, , vol. 77/79, p. 731,734

上下游产品

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50-00-0 106-48-9 2937-59-9
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111870-27-0 63944-31-0 860184-93-6 860185-06-4

海关

海关编码	2932999099
中文概述	2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%