10169-02-5

• 常用中文名：酸性红97
• 常用英文名：acid red 97 (c.i. 22890)
• CAS号：10169-02-5
• 分子式：C₃₂H₂₀N₄Na₂O₈S₂
• 分子量：698.63300
• 相关类别： 染料及颜料 染料 酸性染料
• 发布时间：2018-06-20 12:50:30
• 更新时间：2024-01-21 10:17:21
• 【用途1】
  主要用于皮革、纸张等染色
  【用途2】
  酸性大红 N-2G 用于羊毛、锦纶染色，得艳黄光红色。

名称

• 中文名: 酸性红97
• 英文名: disodium,5-[(2Z)-2-(2-oxonaphthalen-1-ylidene)hydrazinyl]-2-[4-[(2Z)-2-(2-oxonaphthalen-1-ylidene)hydrazinyl]-2-sulfonatophenyl]benzenesulfonate
• 中文别名: 4,4’-二[(2-羟基-1-萘基)偶氮]-[1,1’-联苯]-2,2’-二磺酸二钠盐
• 英文别名: Acid Red 97; Polycor Red GS; Azo Milling Red G; Benzyl Red GS; Milling Red A; MFCD00004072; Korostan Red G; Pharmaglo Red G; Anthra Red G; Crispin Red GM; EINECS 233-439-3

物化性质

• 分子式: C₃₂H₂₀N₄Na₂O₈S₂
• 分子量: 698.63300
• 精确质量: 698.05200
• PSA: 221.06000
• LogP: 9.87180
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：698.051794 Da

  8、标称质量：698 Da

  9、平均质量：698.6327 Da

• 更多:

  1. 性状：溶于水呈橙红色，溶于乙醇为橙色。

  2. 密度（g/mLat 25°C）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,20mmHg）：未确定

  7. 折射率（n20/D）：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,37ºC）：未确定

  12. 饱和蒸气压（kPa,114.4 ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（MPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：溶于水、乙醇、丙酮

MSDS

Version 1.2 Regulation (EC) No 1907/2006 1 - Product and Company Information Product NameACID RED 97 (C.I. 22890) 2 - Hazards Identification 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number ACID RED 97 (C.I. 22890)10169-02-5 233-439-3 None FormulaC32H22N4O8S2.2Na Molecular Weight 698,6500 AMU SynonymsAcid Anthracene Red GA-CF * Acid Red 97 * Airedale Scarlet GM * Alizarine Chrome Red G * Altochrome Scarlet G * Amacid Milling Scarlet G * Anthra Red G * Azo Milling Red G * Belacid Milling Red G * Benzyl Red GS * Benzyl Red MG * C.I. Acid Red 97, disodium salt (8CI) * Calcocid Milling Red G * C.I. 22890 * C.I. Acid Red 97 * Coomassie Milling Scarlet G * Coomassie Milling Scarlet GP * Coriacid Scarlet R * Crispin Red GM * Cyanine Fast Scarlet G * Fenazo Red FG * Hexaderm Red MRG * Korostan Red G * Milling Red A * Milling Scarlet DH * Milling Scarlet 2G * Milling Scarlet R * Naphthalene Leather Scarlet G * Optanol Scarlet GS * Pharmaglo Red G * Polycor Red GS * Shikiso Acid Anthracene Red G * Suminol Brilliant Scarlet DH * Sumitomo Fast Scarlet G * Supranol Scarlet GS * Tertracid Milling Red AGE * Vondamol Brilliant Red G * Xylene Milling Red G 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. SIALwww.molbase.com AFTER SKIN CONTACT In case of contact, immediately wash skin with soap and copious amounts of water. AFTER EYE CONTACT In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. 5 - Fire Fighting Measures EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Emits toxic fumes under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Store in a cool dry place. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) SIALwww.molbase.com or CEN (EU). Respiratory protection is not required. Where protection is desired, use multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash PointN/A FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides. 11 - Toxicological Information RTECS NUMBER: GC5787480 SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. 12 - Ecological Information No data available. 13 - Disposal Considerations SIALwww.molbase.com SUBSTANCE DISPOSAL Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR Non-hazardous for road transport. IMDG Non-hazardous for sea transport. IATA Non-hazardous for air transport. 15 - Regulatory Information COUNTRY SPECIFIC INFORMATION Germany WGK: 3 Self-Classification 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. SIALwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 致突变数据： 细菌-鼠伤寒沙门氏菌：125 ug/plate； CHEMICAL IDENTIFICATION RTECS NUMBER : GC5787480 CHEMICAL NAME : (1,1'-Biphenyl)-2,2'-disulfonic acid, 4,4'-bis((2-hydroxy-1-naphthalenyl)azo)-, disodium salt CAS REGISTRY NUMBER : 10169-02-5 LAST UPDATED : 199701 DATA ITEMS CITED : 3 MOLECULAR FORMULA : C32-H20-N4-O8-S2.2Na MOLECULAR WEIGHT : 698.66 HEALTH HAZARD DATA ACUTE TOXICITY DATA MUTATION DATA TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 125 ug/plate REFERENCE : VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 22,413,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4250 No. of Facilities: 64 (estimated) No. of Industries: 2 No. of Occupations: 8 No. of Employees: 3241 (estimated)

安全

• RTECS号: GC5787480

制备

以联苯胺-2，2^'-双磺酸、2-萘酚为原料。将前者双重氮化，与后者偶合得产物。经盐析、过滤、干燥得成品。