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13436-46-9

13436-46-9结构式
13436-46-9结构式

化源商城直购

中文名 2-乙氧基四氢呋喃
英文名 2-ethoxyoxolane
英文别名 2-Aethoxy-tetrahydro-furan
MFCD00005360
EINECS 236-569-9
Furan,2-ethoxytetrahydro
2-ethoxy-tetrahydro-furan
2-ethoxytrihydrofuran
密度 0.94g/cm3
沸点 171ºC at 760mmHg
分子式 C6H12O2
分子量 116.15800
闪点 16.1ºC
精确质量 116.08400
PSA 18.46000
LogP 1.15940
蒸汽压 0.697mmHg at 25°C
折射率 n20/D 1.414(lit.)
分子结构

摩尔折射率:31.23

2、 摩尔体积(m3/mol):122.2

3、 等张比容(90.2K):279.3

4、 表面张力(dyne/cm):27.2

5、 极化率(10-24cm3):12.38

计算化学

1.疏水参数计算参考值(XlogP):0.9

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积18.5

7.重原子数量:8

8.表面电荷:0

9.复杂度:63.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:1

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1.性状:不可用

2.密度(g/mL,25/4℃):0.908

3.相对蒸汽密度(g/mL,空气=1):不可用

4.熔点(ºC):不可用

5.沸点(ºC,常压):170-172

6.沸点(ºC,5.2kPa):不可用

7.折射率:1.414

8.闪点(ºC):不可用

9.比旋光度(º):不可用

10.自燃点或引燃温度(ºC):不可用

11.蒸气压(kPa,25ºC):不可用

12.饱和蒸气压(kPa,60ºC):不可用

13.燃烧热(KJ/mol):不可用

14.临界温度(ºC):不可用

15.临界压力(KPa):不可用

16.油水(辛醇/水)分配系数的对数值:不可用

17.爆炸上限(%,V/V):不可用

18.爆炸下限(%,V/V):不可用

19.溶解性:不可用


SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name: 2-Ethoxytetrahydrofuran
REACH No.: A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No.: 13436-46-9


SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
F Highly flammableR11
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal wordDanger
Hazard statement(s)
Highly flammable liquid and vapour.
Precautionary statement(s)
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Supplemental Hazardnone
Statements
Other hazards - none

SECTION 3: Composition/information on ingredients
Substances
Formula: C6H12O2
Molecular Weight: 116,16 g/mol
CAS-No.: 13436-46-9
EC-No.: 236-569-9
Hazardous ingredients according to Regulation (EC) No 1272/2008
ComponentClassificationConcentration
2-Hydroxytetrahydrofuran
CAS-No.13436-46-9Flam. Liq. 2; H225<= 100 %
EC-No.236-569-9
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large
fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or
spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of
water.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.

SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition.
Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
Reference to other sections
For disposal see section 13.

SECTION 7: Handling and storage
Precautions for safe handling
Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) AppearanceForm: liquid
b) Odourno data available
c) Odour Thresholdno data available
d) pHno data available
e) Melting point/freezingno data available
point
f) Initial boiling point and 170 - 172 °C - lit.
boiling range
g) Flash point16 °C - closed cup
h) Evapouration rateno data available
i) Flammability (solid, gas) no data available
j) Upper/lowerno data available
flammability or
explosive limits
k) Vapour pressureno data available
l) Vapour densityno data available
m) Relative density0,908 g/cm3 at 25 °C
n) Water solubilityno data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignitionno data available
temperature
q) Decompositionno data available
temperature
r) Viscosityno data available
s) Explosive propertiesno data available
t) Oxidizing propertiesno data available
Other safety information
no data available

SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials
Oxidizing agents, Strong acids
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.

SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available

SECTION 13: Disposal considerations
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.

SECTION 14: Transport information
UN number
ADR/RID: 1993IMDG: 1993IATA: 1993
UN proper shipping name
ADR/RID: FLAMMABLE LIQUID, N.O.S. (2-Hydroxytetrahydrofuran)
IMDG: FLAMMABLE LIQUID, N.O.S. (2-Hydroxytetrahydrofuran)
IATA:Flammable liquid, n.o.s. (2-Hydroxytetrahydrofuran)
Transport hazard class(es)
ADR/RID: 3IMDG: 3IATA: 3
Packaging group
ADR/RID: IIIMDG: IIIATA: II
Environmental hazards
ADR/RID: noIMDG Marine pollutant: noIATA: no
Special precautions for user
no data available

SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

急性毒性:不可用。

生态学数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

符号 GHS02
GHS02
信号词 Danger
危害声明 H225
警示性声明 P210
个人防护装备 Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) F: Flammable;
风险声明 (欧洲) R11
安全声明 (欧洲) 16-29-33
危险品运输编码 UN 1993 3/PG 2
包装等级 II
危险类别 3.1
海关编码 2932190090

~94%

13436-46-9结构式

13436-46-9

文献:Lawson; Klang Synthetic Communications, 1993 , vol. 23, # 22 p. 3205 - 3210

~40%

13436-46-9结构式

13436-46-9

文献:Barton, Derek H. R.; Launay, Franck Tetrahedron, 1997 , vol. 53, # 43 p. 14565 - 14578

~%

13436-46-9结构式

13436-46-9

详细
文献:Poirier, Jean-Marie; Dujardin, Gilles Tetrahedron Letters, 1987 , vol. 28, # 29 p. 3337 - 3340

~13%

13436-46-9结构式

13436-46-9

文献:Polivin, Yu. N.; Trofimova, M. V.; Karakhanov, R. A.; Ageev, E. A. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1992 , vol. 28, # 5 p. 494 - 496 Khimiya Geterotsiklicheskikh Soedinenii, Sbornik, 1992 , # 5 p. 592 - 594

~%

13436-46-9结构式

13436-46-9

详细
文献:Cheliatsidou, Paraskevi; White, Daniel F. S.; Slawin, Alexandra M. Z.; Cole-Hamilton, David J. Dalton Transactions, 2008 , # 18 p. 2389 - 2394

~12%

13436-46-9结构式

13436-46-9

文献:Polivin, Yu. N.; Trofimova, M. V.; Karakhanov, R. A.; Ageev, E. A. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1992 , vol. 28, # 5 p. 494 - 496 Khimiya Geterotsiklicheskikh Soedinenii, Sbornik, 1992 , # 5 p. 592 - 594

~61%

13436-46-9结构式

13436-46-9

文献:Troisi, Luigino; Granito, Catia; Ronzini, Ludovico; Rosato, Francesca; Videtta, Valeria Tetrahedron Letters, 2010 , vol. 51, # 46 p. 5980 - 5983

~%

13436-46-9结构式

13436-46-9

文献:Normant Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1949 , vol. 228, p. 102
海关编码 2932190090
中文概述 2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素 品名, 成分含量, 用途
Summary 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%