76153-06-5

• 常用中文名：5-溴-3-甲基苯-1,2-二胺
• 常用英文名：5-Bromo-3-methylbenzene-1,2-diamine
• CAS号：76153-06-5
• 分子式：C₇H₉BrN₂
• 分子量：201.064
• 发布时间：2018-12-26 12:17:53
• 更新时间：2024-01-12 18:31:04

名称

• 中文名: 5-溴-3-甲基苯-1,2-二胺
• 英文名: 5-Bromo-3-Methylbenzene-1,2-Diamine
• 中文别名: 5-溴-3-甲基邻苯二胺
• 英文别名: 5-Bromo-3-methyl-benzene-1,2-diamine; 4-Bromo-2-methyl-6-nitro-phenylamine; 5-bromo-3-methylbenzene-1,2-diamine; 1,2-Benzenediamine, 5-bromo-3-methyl-; 5-Bromo-3-methyl-1,2-benzenediamine

物化性质

• 密度: 1.6±0.1 g/cm3
• 沸点: 298.8±35.0 °C at 760 mmHg
• 熔点: 63ºC
• 分子式: C₇H₉BrN₂
• 分子量: 201.064
• 闪点: 134.5±25.9 °C
• 精确质量: 199.994904
• PSA: 52.04000
• LogP: 2.02
• 蒸汽压: 0.0±0.6 mmHg at 25°C
• 折射率: 1.670
• 储存条件: 2-8°C

MSDS

Name: 5-Bromo-3-methylbenzene-1 2-diamine Material Safety Data Sheet Synonym: CAS: 76153-06-5 Section 1 - Chemical Product MSDS Name:5-Bromo-3-methylbenzene-1 2-diamine Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 76153-06-5 5-Bromo-3-methylbenzene-1,2-diamine 97+% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 76153-06-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Black Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 59 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H9BrN2 Molecular Weight: 201.07 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids, acid chlorides. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen bromide, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 76153-06-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 5-Bromo-3-methylbenzene-1,2-diamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 22 Do not breathe dust. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 76153-06-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 76153-06-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 76153-06-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 海关编码: 2921590090

合成路线

77811-44-0 ~73% 76153-06-5

文献：F. HOFFMANN-LA ROCHE AG; ALIAGAS-MARTIN, Ignacio; CRAWFORD, James; LEE, Wendy; MATHIEU, Simon; RUDOLPH, Joachim Patent: WO2013/26914 A1, 2013 ; Location in patent: Page/Page column 130 ; WO 2013/026914 A1

570-24-1 ~% 76153-06-5

文献：Organic Process Research and Development, , vol. 7, # 3 p. 318 - 323

120-66-1 ~% 76153-06-5

文献：Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 19, # 12 p. 1035 - 1037

24106-05-6 ~% 76153-06-5

文献：Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 19, # 12 p. 1035 - 1037

95-53-4 ~% 76153-06-5

文献：Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 19, # 12 p. 1035 - 1037

1266383-33-8 ~% 76153-06-5

文献：Bioorganic and Medicinal Chemistry Letters, , vol. 20, # 6 p. 1939 - 1943

上下游产品

上游产品  5
77811-44-0 570-24-1 120-66-1 24106-05-6
95-53-4
下游产品  5
255064-08-5 255064-10-9 77811-41-7 398452-96-5
532934-95-5

海关

海关编码	2921590090
中文概述	2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%