中文名 | 2-烯丙氧基吡啶 |
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英文名 | 2-prop-2-enoxypyridine |
英文别名 |
2-Allyloxy-pyridin
2-ALLYLOXYPYRIDINE Allyl 2-pyridyl ether |
密度 | 1.002g/cm3 |
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沸点 | 194ºC at 760mmHg |
分子式 | C8H9NO |
分子量 | 135.16300 |
闪点 | 69.4ºC |
精确质量 | 135.06800 |
PSA | 22.12000 |
LogP | 1.64640 |
折射率 | 1.505 |
Version 1.0
Regulation (EC) No 1907/2006 1 - Product and Company Information Product Name2-ALLYLOXYPYRIDINE - 50mg 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Harmful if swallowed. Irritating to respiratory system and skin.
Risk of serious damage to eyes. 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number 2-ALLYLOXYPYRIDINE5831-77-6 227-409-9 None FormulaC8H9NO Molecular Weight 135,1600 AMU SynonymsPyridine, 2-(2-propenyloxy)- 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. ALDRICHwww.molbase.com 5 - Fire Fighting Measures EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Emits toxic fumes under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Absorb on sand or vermiculite and place in closed containers for disposal. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Use only in a chemical fume hood. Safety shower and eye bath. GENERAL HYGIENE MEASURES Wash contaminated clothing before reuse. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties AppearancePhysical State: Liquid ALDRICHwww.molbase.com PropertyValueAt Temperature or Pressure pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash PointN/A FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient Log Kow: 1,728 ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Stable: Stable. Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, and nitrogen oxides. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur 11 - Toxicological Information SENSITIZATION Sensitization: Possible sensitizer. Skin: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. The preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship (QSAR) modeling. ROUTE OF EXPOSURE Skin Contact: Causes skin irritation. Skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. 12 - Ecological Information No data available. ALDRICHwww.molbase.com 13 - Disposal Considerations SUBSTANCE DISPOSAL Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. IMDG UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. Inhalation Packing Group I: No Technical Name: Required 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: Xn Harmful. R-PHRASES: 22-37/38-41 Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. S-PHRASES: 26-36/37/39 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. ALDRICHwww.molbase.com Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. ALDRICHwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A |
风险声明 (欧洲) | 20/21/22-36/37/38 |
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安全声明 (欧洲) | 26-36/37/39 |
海关编码 | 2933399090 |
~95% 5831-77-6 |
文献:Yadav; Subba Reddy; Reddy, M. Muralidhar Tetrahedron Letters, 2000 , vol. 41, # 15 p. 2663 - 2665 |
~% 5831-77-6 |
文献:Vavilina; Zicmanis; Mekss; Klavins Chemistry of Heterocyclic Compounds, 2008 , vol. 44, # 5 p. 549 - 558 Khim. Geterotsikl. Soedin., 2008 , # 5 p. 699 - 710 |
~% 5831-77-6 |
文献:Vavilina; Zicmanis; Mekss; Klavins Chemistry of Heterocyclic Compounds, 2008 , vol. 44, # 5 p. 549 - 558 Khim. Geterotsikl. Soedin., 2008 , # 5 p. 699 - 710 |
~% 5831-77-6 |
文献:Westwell, Andrew D.; Williams, Jonathan M. J. Tetrahedron, 1997 , vol. 53, # 38 p. 13063 - 13078 |
~% 5831-77-6 |
文献:Michant'ew et al. Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 1874;engl.Ausg.S.1844 |
上游产品 7 | |
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下游产品 2 | |
海关编码 | 2933399090 |
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中文概述 | 2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
申报要素 | 品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期 |
Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |