Name | methyl 2-(bromomethyl)benzoate |
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Synonyms |
Methyl 2-bromomethyl benzoate
Benzoic acid, 2-(bromomethyl)-, methyl ester Methyl 2-bromomethylbenzoate 2-(Bromomethyl)-benzoic acid methyl ester methyl o-bromomethylbenzoate MFCD00090420 Methyl 2-(bromomethyl)benzoate Benzoic acid,2-(bromomethyl)-,methyl ester methyl 2-(1-bromomethyl)-benzoate methyl ortho-bromomethylbenzoate Methyl-2-(brommethyl)benzolcarboxylat 2-methoxycarbonylbenzyl bromide |
Density | 1.5±0.1 g/cm3 |
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Boiling Point | 293.9±23.0 °C at 760 mmHg |
Melting Point | 30-35°C |
Molecular Formula | C9H9BrO2 |
Molecular Weight | 229.071 |
Flash Point | 131.5±22.6 °C |
Exact Mass | 227.978592 |
PSA | 26.30000 |
LogP | 2.90 |
Vapour Pressure | 0.0±0.6 mmHg at 25°C |
Index of Refraction | 1.560 |
Storage condition | 2~8℃ |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns. Potential Health Effects Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears). Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2417-73-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 153 deg C @4mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H9BrO2 Molecular Weight: 229.07 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2417-73-4 unlisted. LD50/LC50: Not available. Carcinogenicity: Methyl 2-(bromomethyl)benzoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.* Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: II IMO Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: II RID/ADR Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 2417-73-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2417-73-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2417-73-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi |
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HS Code | 2916399090 |
~99% 2417-73-4 |
Literature: SUZHOU RIBO LIFE SCIENCE CO., LTD Patent: US2011/237786 A1, 2011 ; Location in patent: Page/Page column 7 ; |
~76% 2417-73-4 |
Literature: Chen, Gang; Crawford, Jason; Skerlj, Renato Patent: US2005/154201 A1, 2005 ; |
~% 2417-73-4 |
Literature: US2003/13743 A1, ; US 20030013743 A1 |
~% 2417-73-4 |
Literature: US6410561 B1, ; |
~% 2417-73-4 |
Literature: Journal of Organic Chemistry, , vol. 17, p. 1252,1255 |
~% 2417-73-4 |
Literature: US2011/237786 A1, ; |
~% 2417-73-4 |
Literature: Norman, Mark H.; Minick, Douglas J.; Rigdon, Greg C. Journal of Medicinal Chemistry, 1996 , vol. 39, # 1 p. 149 - 157 |
~% 2417-73-4 |
Literature: Journal of Organic Chemistry, , vol. 17, p. 1252,1255 |
~% 2417-73-4 |
Literature: Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 46, p. 510 Chem. Zentralbl., , vol. 85, # II p. 1271 |
Precursor 9 | |
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DownStream 10 | |
HS Code | 2916399090 |
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Summary | 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |