3-picoline n-oxide

Modify Date: 2024-01-02 09:31:15

3-picoline n-oxide Structure
3-picoline n-oxide structure
Common Name 3-picoline n-oxide
CAS Number 1003-73-2 Molecular Weight 109.126
Density 1.0±0.1 g/cm3 Boiling Point 282.3±0.0 °C at 760 mmHg
Molecular Formula C6H7NO Melting Point 37-39 °C(lit.)
MSDS Chinese USA Flash Point 122.6±18.7 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 3-Picoline-N-oxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 282.3±0.0 °C at 760 mmHg
Melting Point 37-39 °C(lit.)
Molecular Formula C6H7NO
Molecular Weight 109.126
Flash Point 122.6±18.7 °C
Exact Mass 109.052765
PSA 25.46000
LogP -0.74
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.513
Water Solubility soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UT5799000
CHEMICAL NAME :
Pyridine, 3-methyl-, 1-oxide
CAS REGISTRY NUMBER :
1003-73-2
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H7-N-O
MOLECULAR WEIGHT :
109.14
WISWESSER LINE NOTATION :
T6NJ AO C1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1689 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TOXIA6 Toxicon. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.1- 1962- Volume(issue)/page/year: 23,815,1985

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39-S24/25
RIDADR NONH for all modes of transport
WGK Germany 1
RTECS UT5799000
HS Code 2933399090

 Synthetic Route

~99%

3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Daiichi Sankyo Company, Limited; Verma, Ashwani Kumar; Nagaswamy, Kumaragurubaran; Sharma, Lalima; Ghosh, Soma; Kale, Balkrishna Ramchandra; Mondal, Aniruddha; Srivastava, Punit Kumar; Dastidar, Sunanda Ghosh; Momin, Rijwan Jaffer; Wagh, Pradip Balu; Pansare, Sonali Nanasaheb; Markad, Pramod Raosaheb; Khairnar, Yogesh Balasaheb; Miyauchi, Rie; Murata, Takeshi; Ishizaki, Masayuki; Nagamochi, Masatoshi; Iimura, Shin Patent: US2014/155398 A1, 2014 ; Location in patent: Paragraph 0429 ;

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3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Chemistry - A European Journal, , vol. 14, # 8 p. 2340 - 2348

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3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Chemistry - A European Journal, , vol. 14, # 8 p. 2340 - 2348

~%

3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Chemistry - A European Journal, , vol. 14, # 8 p. 2340 - 2348

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3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: European Journal of Inorganic Chemistry, , # 14 p. 2894 - 2899

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3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 2193 - 2194 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 2336 - 2337

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3-picoline n-oxide Structure

3-picoline n-oxide

CAS#:1003-73-2

Literature: Journal of Solution Chemistry, , vol. 19, # 11 p. 1113 - 1124

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

3-picoline-oxide
β-Picoline 1-oxide
3-Methylpyridine N-Oxide
EINECS 213-714-4
β-Picoline N-oxide
3-Picoline 1-Oxide
Pyridine, 3-methyl-, 1-oxide
3-methyl-pyridine 1-oxide
3-Methylpyrine-N-Oxide
3-picoline n-oxide
3-Methylpyridine 1-oxide
3-Picoline, 1-oxide (8CI)
B-Picoline-N-oxide
MFCD00006203
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