Methylenaminoacetonitrile

Modify Date: 2024-01-02 13:24:14

Methylenaminoacetonitrile Structure
Methylenaminoacetonitrile structure
 Common Name Methylenaminoacetonitrile
CAS Number 109-82-0 Molecular Weight 68.077
Density 0.8±0.1 g/cm3 Boiling Point 151.2±40.0 °C at 760 mmHg
Molecular Formula C3H4N2 Melting Point 127-130 °C
MSDS N/A Flash Point 45.2±27.3 °C

 Names

Name Methylenaminoacetonitrile
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.8±0.1 g/cm3
Boiling Point 151.2±40.0 °C at 760 mmHg
Melting Point 127-130 °C
Molecular Formula C3H4N2
Molecular Weight 68.077
Flash Point 45.2±27.3 °C
Exact Mass 68.037445
PSA 36.15000
LogP 0.42
Vapour Pressure 3.7±0.3 mmHg at 25°C
Index of Refraction 1.438
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MC1925000
CHEMICAL NAME :
Glycinonitrile, N-methylene-
CAS REGISTRY NUMBER :
109-82-0
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C3-H4-N2
MOLECULAR WEIGHT :
68.09
WISWESSER LINE NOTATION :
NC1NU1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 7,689,1955

 Safety Information

Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S36/37/39-S26-S22
RTECS MC1925000
Packaging Group I; II; III
Hazard Class 6.1
HS Code 2926909090

 Synthetic Route

2,2',2''-(1,3,5-Triazinane-1,3,5-triyl)triacetonitrile structure

2,2',2''-(1,3,5...

CAS#:4560-87-6

~%

Methylenaminoacetonitrile Structure

Methylenaminoac...

CAS#:109-82-0

Literature: Zeitschrift fuer Naturforschung, B: Chemical Sciences, , vol. 42, # 7 p. 810 - 814
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

tetrabutylammonium cyanide structure

tetrabutylammon...

CAS#:71680-52-9

~%

Methylenaminoacetonitrile Structure

Methylenaminoac...

CAS#:109-82-0

Literature: Ber., , vol. 27, p. 59
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

Sodium cyanide structure

Sodium cyanide

CAS#:143-33-9

~%

Methylenaminoacetonitrile Structure

Methylenaminoac...

CAS#:109-82-0

Literature: Monatshefte fuer Chemie, , vol. 98, p. 338 - 352
2,2',2''-(1,3,5-Triazinane-1,3,5-triyl)triacetonitrile structure

2,2',2''-(1,3,5...

CAS#:4560-87-6

~19%

Isocyanomethane structure

Isocyanomethane

CAS#:593-75-9

Methylenaminoacetonitrile Structure

Methylenaminoac...

CAS#:109-82-0

N-(methylimino)acetonitrile structure

N-(methylimino)...

CAS#:59264-17-4

Literature: Helvetica Chimica Acta, , vol. 77, # 8 p. 2209 - 2250
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

~%

Methylenaminoacetonitrile Structure

Methylenaminoac...

CAS#:109-82-0

Literature: Chemische Berichte, , vol. 27, p. 60 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 65, p. 192 Chemische Berichte, , vol. 36, p. 1506

 Customs

HS Code 2926909090
Summary HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

Methyleneiminoacetonitrile
Methyleneglycinonitrile
METHYLENEAMINOACETONITRILE
2-(methylideneamino)acetonitrile
MFCD00001889
(Methyleneamino)acetonitrile
UNII:VUC4O8Q6RO
α-Hydroformamine Cyanide
alpha-Hydroformamine Cyanide
2-(methyleneamino)acetonitrile
Acetonitrile, 2-(methyleneamino)-
EINECS 203-709-5
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