(4-Nitrophenyl)boronic acid

Modify Date: 2024-01-02 14:42:07

(4-Nitrophenyl)boronic acid Structure
(4-Nitrophenyl)boronic acid structure
Common Name (4-Nitrophenyl)boronic acid
CAS Number 24067-17-2 Molecular Weight 166.93
Density 1.4±0.1 g/cm3 Boiling Point 373.7±44.0 °C at 760 mmHg
Molecular Formula C6H6BNO4 Melting Point 285-290°C (dec.)
MSDS USA Flash Point 179.8±28.4 °C
Symbol GHS07
GHS07
Signal Word Warning

 Use of (4-Nitrophenyl)boronic acid


4-Nitrophenylboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name (4-nitrophenyl)boronic acid
Synonym More Synonyms

 (4-Nitrophenyl)boronic acid Biological Activity

Description 4-Nitrophenylboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog
In Vitro 4-Nitrophenylboronic acid 是一种芳基硼酸,已被用于合成苯酚。
References

[1]. Xu, J., Wang, X., Shao, C., et al.Highly efficient synthesis of phenols by copper- catalyzed oxidative hydroxylation of arylboronic acids at room temperature in waterOrg. Lett.12(9)1964-1967(2010)

[2]. Sawant, SD, Hudwekar, AD, Kumar, KAA, et al.Ligand- and base-free synthesis of phenols by rapid oxidation of arylboronic acids using iron(III) oxideTetrahedron Lett.55(4)811-814(2014)

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 373.7±44.0 °C at 760 mmHg
Melting Point 285-290°C (dec.)
Molecular Formula C6H6BNO4
Molecular Weight 166.93
Flash Point 179.8±28.4 °C
Exact Mass 167.038986
PSA 86.28000
LogP 1.32
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.574
Storage condition 2~8℃

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R22
Safety Phrases S26-S36/37/39
RIDADR NONH for all modes of transport
HS Code 2931900090

 Synthetic Route

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Angewandte Chemie - International Edition, , vol. 49, # 32 p. 5515 - 5518

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Journal of the American Chemical Society, , vol. 134, # 28 p. 11667 - 11673

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Synlett, , # 1 art. no. G33904ST, p. 127 - 133

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Synlett, , # 2 p. 266 - 268

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Journal of the American Chemical Society, , vol. 134, # 28 p. 11667 - 11673

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Journal of the American Chemical Society, , vol. 53, p. 713

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(4-Nitrophenyl)boronic acid Structure

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CAS#:24067-17-2

Literature: Journal of Organic Chemistry, , vol. 73, # 12 p. 4662 - 4670

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles14

More Articles
Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.

Org. Lett. 7th ed., 14 , 1930-1933, (2012)

A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combin...

A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.

Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012)

An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl...

Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.

J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012)

The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon a...

 Synonyms

Phenylboronic Acid,9
(4-Nitrophenyl)boronic acid
4-Nitrobenzeneboronic acid p-Nitrophenylboronic acid p-nitro-benzeneboronic acid
para-nitrophenylboronic acid
phenylboronic acid pinacol ester
4-Nitrobenzeneboronic Acid
MFCD00161360
boronic acid,b-(4-nitrophenyl)
4-Borononitrobenzene
Boronic acid, B-(4-nitrophenyl)-
p-nitrophenylboronic acid
4-Nitrophenylboronic Acid
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