苯基三氟甲基硫醚
苯基三氟甲基硫醚结构式
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常用名 | 苯基三氟甲基硫醚 | 英文名 | ((trifluoromethyl)thio)benzene |
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| CAS号 | 456-56-4 | 分子量 | 178.175 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 106.2±40.0 °C at 760 mmHg | |
| 分子式 | C7H5F3S | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 18.0±27.3 °C | |
| 符号 |
GHS02 |
信号词 | Warning |
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Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.
J. Org. Chem. 11th ed., 68 , 4457-4463, (2003) A new and efficient method for the preparation of tri- and difluoromethylsilanes using magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes is reported using tri- and difluoromethyl sulfides, sulfoxides, and sulfones. The byproduct... |
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Synthesis of sulfoxides by the hydrogen peroxide induced oxidation of sulfides catalyzed by iron tetrakis(pentafluorophenyl)porphyrin: scope and chemoselectivity.
J. Org. Chem. 10th ed., 69 , 3586-3589, (2004) The oxidation of sulfides with H(2)O(2) catalyzed by iron tetrakis(pentafluorophenyl)porphyrin in EtOH is an efficient and chemoselective process. With a catalyst concentration 0.03-0.09% of that of the substrate, sulfoxides are obtained with yields generally... |
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Synthesis and structure-activity relationships of benzophenone hydrazone derivatives with insecticidal activity.
Pest Manag. Sci. 2nd ed., 57 , 191-202, (2001) A broad range of benzophenone hydrazone derivatives was prepared and tested against selected chewing insect pests, allowing the analysis of structure-activity relationships. Good activity was found only when the aromatic rings were substituted at the 4-positi... |
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Nucleophilic Trifluoromethylation of C= N Bonds. Dilman AD and Levin VV.
European J. Org. Chem. 2011(5) , 831-841, (2011)
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Oxidation of phenyl trifluoromethyl sulphide: A pulse radiolysis and theoretical study. Shirdhonkar M, et al.
J. Photochem. Photobiol. A: Chem. 195(2) , 277-283, (2008)
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