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戊二腈

戊二腈用途

【用途一】
用于有机合成。

戊二腈名称

[ CAS 号 ]:
544-13-8

[ 中文名 ]:
戊二腈

[ 英文名 ]:
Glutaronitrile

[中文别名 ]:

[英文别名 ]:

1,3-DICYANOPROPANE
Glutarodinitrile
Pentanedinitrlie
Pentanedinitrile
Glutaric dinitrile
3-thiaglutaronitrile
EINECS 208-861-6
glutaric acid dinitrile
Glutaronitrile
Glutarsaeuredinitril

戊二腈物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
287.3±13.0 °C at 760 mmHg

[ 熔点 ]:
−29 °C(lit.)

[ 分子式 ]:
C₅H₆N₂

[ 分子量 ]:
94.115

[ 闪点 ]:
148.4±13.7 °C

[ 精确质量 ]:
94.053101

[ PSA ]:
47.58000

[ LogP ]:
-0.72

[ 外观性状 ]:
透明无色至淡黄色液体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.425

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类、食品添加剂分开存放

[ 水溶解性 ]:
soluble

戊二腈MSDS

戊二腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: YI3500000

CHEMICAL NAME :: 1,3-Trimethylenedinitrile

CAS REGISTRY NUMBER :: 544-13-8

BEILSTEIN REFERENCE NO. :: 1738385

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C5-H6-N2

MOLECULAR WEIGHT :: 94.13

WISWESSER LINE NOTATION :: NC3CN

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 266 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PHLIDQ Pharmacochemistry Library. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1977- Volume(issue)/page/year: 8,73,1985

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Gastrointestinal - nausea or vomiting

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 3,77,1897

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 18 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - convulsions or effect on seizure threshold

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 3,77,1897

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Bird - pigeon

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Gastrointestinal - nausea or vomiting

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 3,77,1897

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Amphibian - frog

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 3,77,1897

戊二腈安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H312 + H332

[ 警示性声明 ]:
P280-P301 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/21/22;R36/38

[ 安全声明 (欧洲) ]:
S36/37-S36/37/39-S26

[ 危险品运输编码 ]:
UN 2810 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
YI3500000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2926909090

戊二腈合成路线

戊二腈上下游产品

戊二腈上游产品

戊二腈下游产品

戊二腈制备

由二溴丙烷与氰化钠反应而得。将氰化钠溶于水，加入二溴丙烷的乙醇，冷却，滤去沉淀。将母液用乙酸乙酯提出取，用水洗涤提取液。经碳酸钾干燥后回收乙酸乙酯，剩余物进行减压蒸馏，收集144-147℃（1.73kPa）馏分即为成品，收率约80%。

戊二腈海关

[ 海关编码 ]: 2926909090

[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

戊二腈文献

Complexation of uranium(VI) with glutarimidoxioxime: thermodynamic and computational studies.

Dalton Trans. 44 , 13835-44, (2015)

The complex formation between a cyclic ligand glutarimidoxioxime (denoted as HL(III) in this paper) and UO2(2+) is studied by potentiometry and microcalorimetry. Glutarimidoxioxime (HL(III)), together...

Interaction of High Flash Point Electrolytes and PE-Based Separators for Li-Ion Batteries.

Int. J. Mol. Sci. 16 , 20258-76, (2015)

In this study, promising electrolytes for use in Li-ion batteries are studied in terms of interacting and wetting polyethylene (PE) and particle-coated PE separators. The electrolytes are characterize...

Molecular diffusion and dc conductivity perfectly correlated with molecular rotational dynamics in a plastic crystalline electrolyte.

Phys. Chem. Chem. Phys. 17 , 16053-7, (2015)

We probe the ionic conduction and the molecular dynamics in a pure and lithium-salt doped dinitrile molecular plastic crystal. While the diffusion of the Li(+) ions is decoupled from the molecular reo...

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戊二腈