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4-硝基二苯醚

4-硝基二苯醚用途

【用途一】
有机合成中间体。

4-硝基二苯醚名称

[ CAS 号 ]:
620-88-2

[ 中文名 ]:
对硝基二苯醚

[ 英文名 ]:
4-NITROPHENYL PHENYL ETHER

[中文别名 ]:

[英文别名 ]:

EINECS 210-656-1
MFCD00007320
1-nitro-4-phenoxybenzene

4-硝基二苯醚物理化学性质

[ 密度 ]:
1.12g/cm3

[ 沸点 ]:
320 °C(lit.)

[ 熔点 ]:
53-56 °C(lit.)

[ 分子式 ]:
C₁₂H₉NO₃

[ 分子量 ]:
215.20500

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
215.05800

[ PSA ]:
55.05000

[ LogP ]:
3.91030

[ 折射率 ]:
1.564

[ 储存条件 ]:
室温

4-硝基二苯醚MSDS

详细MSDS(安全技术说明书)

4-硝基二苯醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KO2680000

CHEMICAL NAME :: Ether, 4-nitrophenyl phenyl

CAS REGISTRY NUMBER :: 620-88-2

BEILSTEIN REFERENCE NO. :: 2051911

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C12-H9-N-O3

MOLECULAR WEIGHT :: 215.22

WISWESSER LINE NOTATION :: WNR DOR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 100 ug/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 67,123,1979

4-硝基二苯醚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
3077.0

[ WGK德国 ]:
3

[ RTECS号 ]:
KO2680000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
2909309090

4-硝基二苯醚上下游产品

4-硝基二苯醚上游产品

4-硝基二苯醚下游产品

4-硝基二苯醚制备

将160g苯酚与80g氢氧化钾混合，加热至130-140℃使碱溶完。冷至100-110℃，加入0.5g活性铜粉及78.8g对硝基氯苯，搅拌加热至150-160℃，反应沸腾时加入氯化钾离析，停止加热，不再沸腾再加入78.8g对硝基氯苯，重复如前操作一次。将反应产物倾入50g氢氧化钠的1.5L冰水溶液中，除去酚，对硝基二苯醚沉淀析出，将滤集的粗品减压蒸馏，得173-177g成品，收率80-82%。

4-硝基二苯醚海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

4-硝基二苯醚文献

Mutagenicity of 4-nitrodiphenyl ether and its metabolites.

Toxicol. Lett. 34(1) , 13-21, (1986)

The mutagenic potential of 4-nitrodiphenyl ether (NDE) an intermediate of herbicides and an anthelmintic drug, and its reduced products (-NO, -NHOH) were investigated in the Ames test. All the three c...

Mutagenic activity of possible metabolites of 4-nitrobiphenyl ether.

Chem. Biol. Interact. 51(1) , 49-62, (1984)

A series of possible metabolites--4-nitrosobiphenyl ether (4-NO), 4-hydroxylaminobiphenyl ether (4-NHOH), 4-aminobiphenyl ether (4-NH2), 4-hydroxyacetylaminobiphenyl ether (4-N(OH)Ac), 4-acetoxyacetyl...

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