21797-13-7

• 常用中文名：四乙腈四氟硼酸钯
• 常用英文名：TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
• CAS号：21797-13-7
• 分子式：C₈H₁₂B₂F₈N₄Pd
• 分子量：444.23700
• 相关类别： 有机原料 有机金属类化合物 有机钯
• 发布时间：2018-08-13 15:05:22
• 更新时间：2024-01-05 07:42:46
• 下载msds

名称

• 中文名: 四(乙腈)四氟硼酸钯(II)
• 英文名: acetonitrile,palladium(2+),ditetrafluoroborate
• 中文别名: 四乙腈四氟硼酸钯
• 英文别名: [Pd(NCMe)4][BF4]2; [(MeCN)4Pd][BF4]2; ditetrafluoroborate; [Pd(MeCN)4](tetrafluoroborate)2; MFCD00043297; [Pd(CH3CN)4][BF4]2; [Pd(acetonitrile)4](BF4)2; [Pd(MeCN)4](BF4)2; Palladium(II) tetrafluoroborate tetraacetonitrile complex

物化性质

• 熔点: 230ºC
• 分子式: C₈H₁₂B₂F₈N₄Pd
• 分子量: 444.23700
• 精确质量: 444.01600
• PSA: 95.16000
• LogP: 4.71952
• 外观性状: Powder | Yellow
• 储存条件:

  2-8℃

• 稳定性:

  如果遵照规格使用和储存则不会分解

  避免接触氧化物，空气
• 水溶解性: Soluble in water
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:14

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积95.2

  7.重原子数量:23

  8.表面电荷:0

  9.复杂度:48.4

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:7

• 更多:

  1.性状：黄色粉末

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC ):230

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Name: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet Synonym: CAS: 21797-13-7 Section 1 - Chemical Product MSDS Name:Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 21797-13-7 Tetrakis(acetonitrile)palladium(II) te unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed.Air sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 21797-13-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 230 deg C (dec.) Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Soluble. Specific Gravity/Density: Molecular Formula: C8H12B2F8N4Pd Molecular Weight: 444.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas, boron oxides. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 21797-13-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 21797-13-7: 2 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 21797-13-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 21797-13-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H332
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xn:Harmful;
• 风险声明 (欧洲): R20
• 安全声明 (欧洲): S22-S38-S36/37/39
• 危险品运输编码: UN2811
• WGK德国: 3
• 包装等级: III
• 海关编码: 29310099

合成路线

429-42-5 3375-31-3 75-05-8 ~57% 21797-13-7

文献：Journal of the American Chemical Society, , vol. 129, # 8 p. 2246 - 2247

上下游产品

上游产品  3
429-42-5 3375-31-3 75-05-8
下游产品  0