130-20-1

• 常用中文名：还原蓝 6
• 常用英文名：Vat Blue 6
• CAS号：130-20-1
• 分子式：C₂₈H₁₂Cl₂N₂O₄
• 分子量：511.31200
• 相关类别： 染料及颜料 染料 还原染料
• 发布时间：2018-06-23 13:11:41
• 更新时间：2024-01-06 18:45:45
• Vat Blue 6 is a blue dye.

名称

• 中文名: 颜料蓝64
• 英文名: Vat Blue 6
• 中文别名: 士林漂蓝 BC; 还原蓝 6; 士林漂蓝BCS
• 英文别名: Blue BC; 7,16-dichloro-6,15-dihydro-dinaphtho[2,3-a,2',3'-h]phenazine-5,9,14,18-tetraone; 3,3'-dichloroindanthrone; Pigment Blue 64; Blue K; C Blue 9; Vat Blue K; AO204; EINECS 204-980-2; 7,16-Dichlor-6,15-dihydro-dinaphtho[2,3-a,2',3'-h]phenazin-5,9,14,18-tetraon; C Blue No.9; Dichloroindanthrone; 7,16-Dichloro-6,15-dihydro-5,9,14,18-anthrazinetetrone; Vat Blue KD

物化性质

• 密度: 1.591g/cm3
• 沸点: 788.5ºC at 760mmHg
• 分子式: C₂₈H₁₂Cl₂N₂O₄
• 分子量: 511.31200
• 闪点: 430.6ºC
• 精确质量: 510.01700
• PSA: 99.86000
• LogP: 5.44740
• 蒸汽压: 7.83E-25mmHg at 25°C
• 折射率: 1.746
• 储存条件: 室温，干燥
• 计算化学:

  1.疏水参数计算参考值（XlogP）:6.1

  2.氢键供体数量:2

  3.氢键受体数量:6

  4.可旋转化学键数量:0

  5.互变异构体数量:25

  6.拓扑分子极性表面积92.3

  7.重原子数量:36

  8.表面电荷:0

  9.复杂度:926

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1.性状：蓝绿色粉末。

  2.溶解性：不溶于水、丙酮、乙醇、甲苯，微溶于氯仿 (热)、邻氯苯酚、吡啶 (热)。于浓硫酸中呈棕色，稀释后呈蓝色。于保险粉碱性溶液中呈绿光蓝色，于酸性液中呈红光蓝色。

MSDS

Material Safety Data Sheet Section1. Identification of the substance Product Name: Vat blue 6 Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. Section3. Composition/information on ingredients. Ingredient name:Vat blue 6 CAS number:130-20-1 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Store in closed vessels. Storage: Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified Boiling point:No data No data Melting point: Flash point:No data Density:No data Molecular formula:C28H12Cl2N2O4 Molecular weight:511.3 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information Non-harzardous for air and ground transportation. Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : CB8760000 CHEMICAL NAME : 5,9,14,18-Anthrazinetetrone, 7,16-dichloro-6,15-dihydro- CAS REGISTRY NUMBER : 130-20-1 BEILSTEIN REFERENCE NO. : 0068486 LAST UPDATED : 199710 DATA ITEMS CITED : 8 MOLECULAR FORMULA : C28-H12-Cl2-N2-O4 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >10 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 420 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1800 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GNAMAP Gigiena Naselennykh Mest. Hygiene in Populated Places. (Izdatel'stvo Zdorov'ya, Kiev, USSR) V.7- 1967- Volume(issue)/page/year: 14,152,1975 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 25 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GNAMAP Gigiena Naselennykh Mest. Hygiene in Populated Places. (Izdatel'stvo Zdorov'ya, Kiev, USSR) V.7- 1967- Volume(issue)/page/year: 14,152,1975 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 30 gm/kg/30D-I TOXIC EFFECTS : Kidney, Ureter, Bladder - proteinuria Kidney, Ureter, Bladder - other changes in urine composition Blood - changes in leukocyte (WBC) count REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X8842 No. of Facilities: 463 (estimated) No. of Industries: 8 No. of Occupations: 13 No. of Employees: 24086 (estimated) No. of Female Employees: 20898 (estimated)

安全

• 海关编码: 2933990090

合成路线

6374-76-1 ~% 130-20-1

文献：DE656944 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 24, p. 868 US2030876 , ;

81-77-6 ~% 130-20-1

文献：US2413514 , ;

117-01-1 ~% 130-20-1

文献：US2056593 , ;

84-42-4 ~% 130-20-1

文献：DE476811 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 16, p. 1317

上下游产品

上游产品  4
6374-76-1 81-77-6 117-01-1 84-42-4
下游产品  0

制备

以 2-氨基蒽醌为原料，经碱熔后加入硫酸、二氧化锰溶解，然后通入氯气氯化，经结晶、酸洗、还原离析、过滤、粉碎、干燥得成品。

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%