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814-80-2生产厂家

814-80-2价格

814-80-2

814-80-2结构式
814-80-2结构式

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中文名 乳酸钙
英文名 Calcium Lactate
中文别名 Α-羟基-丙酸钙五水化合物
英文别名 Calcium dilactate
EINECS 212-406-7
MFCD00150986
Propanoic acid, 2-hydroxy-, calcium salt (2:1)
Calcium bis(2-hydroxypropanoate)
Calcium lactate
沸点 227.6ºC at 760 mmHg
分子式 C6H10CaO6
分子量 218.218
闪点 109.9ºC
精确质量 218.010330
PSA 120.72000
外观性状 白色粉末
储存条件

保持容器密封,储存在阴凉,干燥的地方

稳定性

常温常压下稳定,避免氧化物接触

外观为白色的颗粒或粉末。几乎无臭,基本无味,在水中缓慢溶解成透明或微浑浊的溶液。易溶于热水,几乎不溶于乙醇、乙醚及氯仿,在空气中稍风化,加热到150℃则成无水物。
计算化学

1、 氢键供体数量:2

2、 氢键受体数量:6

3、 可旋转化学键数量:0

4、 拓扑分子极性表面积(TPSA):121

5、 重原子数量:13

6、 表面电荷:0

7、 复杂度:53.5

8、 同位素原子数量:0

9、 确定原子立构中心数量:0

10、 不确定原子立构中心数量:2

11、 确定化学键立构中心数量:0

12、 不确定化学键立构中心数量:0

13、 共价键单元数量:3

更多

1. 性状:白色至乳白色结晶或粉末,基本无臭无味。

2. 密度(g/mL,25/4℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:易溶于热水成透明或微混浊的溶液,不溶于乙醇、氯仿和乙醚。

Name: Calcium Lactate Material Safety Data Sheet
Synonym: Lactic acid, calcium salt; calphosan; conclyte calcium; 2-hydroxypropanoc acid, calcium salt
CAS: 814-80-2
Section 1 - Chemical Product MSDS Name:Calcium Lactate Material Safety Data Sheet
Synonym:Lactic acid, calcium salt; calphosan; conclyte calcium; 2-hydroxypropanoc acid, calcium salt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
814-80-2 Calcium Lactate 100 % 212-406-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 814-80-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C6H10O6Ca.5H2O
Molecular Weight: 308.2134

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidants.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, calcium oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 814-80-2: OD4150000 LD50/LC50:
Not available.
Carcinogenicity:
Calcium Lactate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 814-80-2: No information available.
Canada
CAS# 814-80-2 is listed on Canada's DSL List.
CAS# 814-80-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 814-80-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

急性毒性:小鼠静脉LD50:140mg/kg

生态学数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OD4150000
CAS REGISTRY NUMBER :
814-80-2
LAST UPDATED :
199707
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H10-O6.Ca

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
140 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPHAA3 Journal of the American Pharmaceutical Association. (Washington, DC) V.1-28, 1912-39; New series: V.1-17, 1961-77. Volume(issue)/page/year: 27,484,1938 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 80372 No. of Facilities: 1705 (estimated) No. of Industries: 10 No. of Occupations: 19 No. of Employees: 18131 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 80372 No. of Facilities: 828 (estimated) No. of Industries: 7 No. of Occupations: 21 No. of Employees: 11944 (estimated) No. of Female Employees: 7389 (estimated)

风险声明 (欧洲) 36/37/38
安全声明 (欧洲) S26-S36/37/39
海关编码 2918110000

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814-80-2结构式

814-80-2

文献:EP839459 B1, ;

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814-80-2结构式

814-80-2

文献:WO2010/4501 A2, ; Page/Page column 56 - 58 ;

1.大米经高压糊化,用水稀释冷至50-53℃,接入黑曲霉菌和德氏乳酸杆菌,发酵得到代谢产物乳酸,然后加入磷酸钙中和,得到粗乳酸钙,最后再进行精制,或者用碳酸钙中和稀乳酸液,再将溶液蒸发而制得。精制过程是利用氯化镁和氢氧化钙作用生成的氢氧化镁,它有凝聚作用的性质,使发酵液中的部分杂质和蛋白质凝聚后除去,然后经真空浓缩,结晶,精制而得乳酸钙。(1)发酵法。以碳酸钙为中和剂进行乳酸发酵,用石灰水中和发酵液后经二次结晶,直接生产乳酸钙。发酵原料可用大米糊化糖化液或米粉(玉米粉)双酶水解液,具体参考乳酸发酵。
(2)中和法。在50%的成品乳酸溶液中加入氢氧化钙或氧化钙进行中和反应,然后过滤除去不溶性杂质,再经过冷却结晶、分离、干燥得成品。此法工艺简单,但成本较高。发酵法
以碳酸钙为中和剂进行乳酸发酵,用石灰水中和发酵液后经二次结晶,直接生产乳酸钙。发酵原料可用大米糊化糖化液或米粉(玉米粉)双酶水解液,具体参考乳酸发酵。
3.中和法
在50%的成品乳酸溶液中加入氢氧化钙或氧化钙进行中和反应,然后过滤除去不溶性杂质,再经冷却结晶、分离、干燥得成品。此法工艺简单,但成本较高。
2C3H6O3+Ca(OH)2→(C3H5O3)2Ca+2H2O

4.用乳酸水溶液与氢氧化钙或碳酸钙反应,再经精制即得产品。反应式如下。

814-80-2 preparation

海关编码 2918110000
中文概述 2918110000. 乳酸及其盐和酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
监管条件 A.入境货物通关单 B.出境货物通关单
检验检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary 2918110000. lactic acid, its salts and esters. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%