8-Bromoquinoline
8-Bromoquinoline structure
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Common Name | 8-Bromoquinoline | ||
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| CAS Number | 16567-18-3 | Molecular Weight | 208.055 | |
| Density | 1.6±0.1 g/cm3 | Boiling Point | 303.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C9H6BrN | Melting Point | 58-59 °C | |
| MSDS | Chinese USA | Flash Point | 132.8±19.8 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Reactivity of the bifunctional ambiphilic molecule 8-(dimesitylboryl)quinoline: hydrolysis and coordination to Cu(I), Ag(I) and Pd(II).
Dalton Trans. 39(45) , 11081-90, (2010) The ambiphilic molecule 8-(dimesitylboryl)quinoline (1) was synthesized by treatment of 8-bromoquinoline or 8-iodoquinoline with n-BuLi followed by dimesitylboronfluoride. Hydrolysis of 1 is unusually rapid compared to bulky triorganoboranes with the sequenti... |
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Direct synthesis of tricyclic 5H-pyrido[3,2,1-ij]quinolin-3-one by domino palladium catalyzed reaction.
Org. Biomol. Chem. 4(20) , 3760-2, (2006) Unexpectedly, the palladium catalyzed coupling reaction of acrolein with 8-bromoquinoline gave 5H-pyrido[3,2,1-ij]quinolin-3-one in a single step. |
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Facile synthesis of 8-substituted quinolines. Suggs JW and Pearson GDN.
J. Org. Chem. 45(8) , 1514-15, (1980)
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Synthesis and coordination behaviour of the new (8-quinolyl) cyclopentadienyl ligand. Enders M, et al.
J. Organomet. Chem. 622(1) , 66-73, (2001)
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Synthesis of n, n'-biquinolines by a coupling reaction of bromoquinolines using organonickel (0) complexes. Benito Y, et al.
Appl. Organomet. Chem. 1(6) , 535-40, (1987)
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Direct heteroarylation of 5-bromothiophen-2-ylpyridine and of 8-bromoquinoline via palladium-catalysed C-H bond activation: simpler access to heteroarylated nitrogen-based derivatives. Laroche J, et al.
Catal. Sci. Tech. 3(8) , 2072-2080, (2013)
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