BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) structure
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Common Name | BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) | ||
|---|---|---|---|---|
| CAS Number | 887919-35-9 | Molecular Weight | 708.07 | |
| Density | N/A | Boiling Point | 349.1ºC at 760 mmHg | |
| Molecular Formula | C32H56Cl2N2P2Pd | Melting Point | N/A | |
| MSDS | USA | Flash Point | 164.9ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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New air-stable catalysts for general and efficient suzuki-miyaura cross-coupling reactions of heteroaryl chlorides.
Org. Lett. 8 , 1787, (2006) [reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides a... |
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Zn-mediated, Pd-catalyzed cross-couplings in water at room temperature without prior formation of organozinc reagents.
J. Am. Chem. Soc. 131 , 15592, (2009) Mix in water, stir. That is all that is required in this new approach to sp(3)-sp(2) cross-couplings between an alkyl iodide and an aryl bromide, both potentially bearing functionality. They react under catalysis by Pd(0) in the presence of zinc powder, aided... |
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