Hoveyda-Grubbs II

Hoveyda-Grubbs II Structure
Hoveyda-Grubbs II structure
Common Name Hoveyda-Grubbs II
CAS Number 301224-40-8 Molecular Weight 626.622
Density N/A Boiling Point N/A
Molecular Formula C31H38Cl2N2ORu Melting Point 216-220ºC(lit.)
MSDS USA Flash Point N/A

Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis.

Org. Lett. 9 , 1589, (2007)

[reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ortho-substituted phenyl (e.g., tolyl). These new catalysts of...

Sequential catalysis: a metathesis/dihydroxylation sequence.

Angew. Chem. Int. Ed. Engl. 45 , 1900, (2006)

Ruthenium catalysed cross metathesis with fluorinated olefins.

Chem. Commun. (Camb.) , 1692, (2001)

The E-selective cross metathesis (CM) of fluorinated olefins with various functionalised alkenes in good to excellent yields is reported.

Ring-opening metathesis/oxy-cope rearrangement: a new strategy for the synthesis of bicyclic medium ring-containing compounds.

J. Am. Chem. Soc. 125 , 14901, (2003)

Ring-opening/ring-closing metathesis on cyclobutene-containing substrates with angular oxygen functionality provides a stereospecific introduction of 1,5-bis-dienes required for an anion-accelerated oxy-Cope rearrangement. The reaction sequence offers general...

Schrodi, Y.; Pederson, R. L.

Aldrichimica Acta 40th ed.,, 45, (2007)

Vougioukalakis, G. C.; Grubbs, R. H.

Chem. Rev. 110th ed.,, 1746, (2010)

Grubbs, R. H.

Tetrahedron 60th ed.,, 7117, (2004)

Trnka, T. M.; Grubbs, R. H.

Acc. Chem. Res. 34th ed.,, 18, (2001)

Fürstner, A.

Angew. Chem. Int. Ed. Engl. 39th ed.,, 3012, (2000)

Schuster, M.; Blechert, S.

Angew. Chem. Int. Ed. Engl. 36th ed.,, 2036, (1997)