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26644-46-2

26644-46-2 structure
26644-46-2 structure
  • Name: Triforine
  • Chemical Name: triforine
  • CAS Number: 26644-46-2
  • Molecular Formula: C10H14Cl6N4O2
  • Molecular Weight: 434.96
  • Catalog: Chemical pesticide Fungicide Other fungicides
  • Create Date: 2018-07-14 17:48:23
  • Modify Date: 2024-01-02 19:05:31
  • Triforine (CELA W 524), a systemic fungicide, was shown to display a moderate to distinct fungitoxic activity in vitro towards several pathogenic and non-pathogenic fungi[1].
Name triforine
Synonyms Saprol
N,N'-(1,4-piperazinediyl bis (2,2,2-trichloro) ethylidene) bis formamide
Triforin
CW 524
N,N’-[1,4-piperazinediylbis(2,2,2-trichloroethylidene)]bis[formamide]
CELA 50
N,N'-[1,4-Piperazinediylbis(2,2,2-trichloro-1,1-ethanediyl)]diformamide
Caswell No. 890AA
Triforine
EINECS 247-872-0
1,4-bis-(2,2,2-trichloro-1-formamidoethyl)-piperazine
N,N'-[Piperazine-1,4-diylbis(2,2,2-trichloroethane-1,1-diyl)]diformamide
N-[2,2,2-trichloro-1-[4-(2,2,2-trichloro-1-formamidoethyl)piperazin-1-yl]ethyl]formamide
Formamide, N,N'-[1,4-piperazinediylbis(2,2,2-trichloroethylidene)]bis-
N,N’-{piperazine-1,4-diylbis[(trichloromethyl)methylene]}diformamide
MFCD00055521
N,N'-[Piperazin-1,4-diylbis(2,2,2-trichlorethan-1,1-diyl)]diformamid
N,N'-(2,2,2,2',2',2'-hexachloro-1,1'-piperazine-1,4-diyl-diethyl)-bis-formamide
Biformylchlorazin
Funginex
N,N’-[piperazine-1,4-diylbis(2,2,2-trichloroethane-1,1-diyl)]diformamide
Description Triforine (CELA W 524), a systemic fungicide, was shown to display a moderate to distinct fungitoxic activity in vitro towards several pathogenic and non-pathogenic fungi[1].
Related Catalog
References

[1]. Fuchs, A, et al. Laboratory and greenhouse evaluation of a new systemic fungicide, NN'-bis-(1-formamido-2,2,2,-trichloroethyl)-piperazine (CELA W 524) [1971]. Netherlands journal of plant pathology. ISSN : 0028-2944.

Density 1.6±0.1 g/cm3
Boiling Point 561.5±50.0 °C at 760 mmHg
Melting Point 155ºC (decomposes)
Molecular Formula C10H14Cl6N4O2
Molecular Weight 434.96
Flash Point 293.4±30.1 °C
Exact Mass 431.924805
PSA 64.68000
LogP 4.61
Vapour Pressure 0.0±1.5 mmHg at 25°C
Index of Refraction 1.571

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TK9200000
CHEMICAL NAME :
Piperazine, 1,4-bis(1-formamido-2,2,2-trichloroethyl)-
CAS REGISTRY NUMBER :
26644-46-2
BEILSTEIN REFERENCE NO. :
0626358
LAST UPDATED :
199612
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C10-H14-Cl6-N4-O2
MOLECULAR WEIGHT :
434.98
WISWESSER LINE NOTATION :
T6N DNTJ AYMVHXGGG DYMVHXGGG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
180 uL/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Taste) - change in function
REFERENCE :
AJEMEN American Journal of Emergency Medicine. (WB Saunders, Philadelphia, PA) V.1- 1983- Volume(issue)/page/year: 4,554,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 4,81,1976/1977
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>4500 mg/m3/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,853,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,853,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A413,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>6 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,853,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A413,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A413,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,853,1991 *** REVIEWS *** TOXICOLOGY REVIEW 27ZTAP "Clinical Toxicology of Commercial Products--Acute Poisoning," 3rd ed., Gleason, M.N., et al., eds., Baltimore, Williams and Wilkins, 1969 Volume(issue)/page/year: 3,126,1969 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2601 No. of Facilities: 31 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 644 (estimated) No. of Female Employees: 123 (estimated)
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H332
Hazard Codes Xn
Risk Phrases 52/53-20
Safety Phrases 61
RIDADR UN3077 (solid); UN3082 (liquid)
RTECS TK9200000
HS Code 2933599019
HS Code 2933599019
Summary 2933599019 n,n'-(piperazine-1,4-diylbis(2,2,2-trichloroethane-1,1-diyl))diformamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

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