Dimethyl(2-methyl-2-propanyl)silanecarbonitrile structure
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Common Name | Dimethyl(2-methyl-2-propanyl)silanecarbonitrile | ||
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CAS Number | 56522-24-8 | Molecular Weight | 141.286 | |
Density | 0.8±0.1 g/cm3 | Boiling Point | 166.4±9.0 °C at 760 mmHg | |
Molecular Formula | C7H15NSi | Melting Point | 76-79ºC(lit.) | |
MSDS | Chinese USA | Flash Point | 54.5±18.7 °C | |
Symbol |
GHS06 |
Signal Word | Danger |
Name | [tert-butyl(dimethyl)silyl]formonitrile |
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Synonym | More Synonyms |
Density | 0.8±0.1 g/cm3 |
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Boiling Point | 166.4±9.0 °C at 760 mmHg |
Melting Point | 76-79ºC(lit.) |
Molecular Formula | C7H15NSi |
Molecular Weight | 141.286 |
Flash Point | 54.5±18.7 °C |
Exact Mass | 141.097382 |
PSA | 23.79000 |
LogP | 2.23 |
Vapour Pressure | 1.8±0.3 mmHg at 25°C |
Index of Refraction | 1.412 |
Symbol |
GHS06 |
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Signal Word | Danger |
Hazard Statements | H301-H311-H331 |
Precautionary Statements | P261-P280-P301 + P310-P311 |
Personal Protective Equipment | Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges |
Hazard Codes | T |
Risk Phrases | R23/24/25 |
Safety Phrases | 36/37/39-45 |
RIDADR | UN 2811 6.1/PG 1 |
WGK Germany | 3 |
Packaging Group | III |
Hazard Class | 6.1(b) |
~82% Dimethyl(2-meth... CAS#:56522-24-8 |
Literature: Bulletin of the Chemical Society of Japan, , vol. 60, # 6 p. 2257 - 2258 |
~91% Dimethyl(2-meth... CAS#:56522-24-8 |
Literature: Journal of Organic Chemistry, , vol. 51, # 25 p. 5010 - 5013 |
~97% Dimethyl(2-meth... CAS#:56522-24-8 |
Literature: Chemische Berichte, , vol. 126, # 1 p. 177 - 190 |
~71% Dimethyl(2-meth... CAS#:56522-24-8 |
Literature: Journal of Organic Chemistry, , vol. 51, # 18 p. 3545 - 3548 |
~% Dimethyl(2-meth... CAS#:56522-24-8 |
Literature: Journal of Organometallic Chemistry, , vol. 139, p. 21 - 30 |
Stereocontrolled access to orthogonally protected anti,anti-4-aminopiperidine-3,5-diols through chemoselective reduction of enantiopure beta-lactam cyanohydrins.
J. Org. Chem. 72(21) , 7980-91, (2007) The cyanosilylation of enantiopure 4-oxoazetidine-2-carbaldehydes with tert-butyldimethylsilyl cyanide was promoted by either molecular sieves or catalytic amount of sodium carbonate to give O-silylat... |
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J. Org. Chem. 51 , 5010, (1986)
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Addition of tert-butyldimethyl-or tert-butyldiphenylsilyl cyanide to hindered ketones. Golinski M, et al.
J. Org. Chem. 58(1) , 159-64, (1993)
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Dimethyl(2-methyl-2-propanyl)silanecarbonitrile |
t-Bu(Me)2SiCN |
MFCD00054923 |
tert-Butyl-cyano-dimethylsilane |
tert-Butyldimethylsilyl cyanide |
Silanecarbonitrile, 1-(1,1-dimethylethyl)-1,1-dimethyl- |
tert-butyldimethylsilylnitrile |