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茴香酮

茴香酮用途

(+)-Fenchone 存在于多种香精油中,如 Foenicufum vulgare Mill. 和 Lavandula stoechas。Fenchone 在食品和香水中用作调味剂。

茴香酮名称

[ CAS 号 ]:
4695-62-9

[ 中文名 ]:
(+)-葑酮

[ 英文名 ]:
1,3,3-Trimethyl-2-norbornanone

[中文别名 ]:

[英文别名 ]:

d-Fenchone
(S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
(1S,4R)-fenchone
(1S,4R)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
d-1,3,3-Trimethyl-2-norbornanone
MFCD00070689
EINECS 225-160-0
2-Norbornanone, 1,3,3-trimethyl-, (1S,4R)-(+)-
d-1,3,3-Trimethyl-2-norcamphanone
(-)-FENCHONE

茴香酮生物活性

[ 描述 ]:

(+)-Fenchone 存在于多种香精油中,如 Foenicufum vulgare Mill. 和 Lavandula stoechas。Fenchone 在食品和香水中用作调味剂。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[体外研究]

(+)-Fenchone是Fenchone的一种对映体,存在于许多精油中[1]。

[参考文献]

[1]. Uzi Ravid, et al. Chiral gc analysis of enantiomerically pure fenchone in essential oils.

茴香酮物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
193.5±0.0 °C at 760 mmHg

[ 熔点 ]:
5-6ºC(lit.)

[ 分子式 ]:
C₁₀H₁₆O

[ 分子量 ]:
152.233

[ 闪点 ]:
69.3±10.7 °C

[ 精确质量 ]:
152.120117

[ PSA ]:
17.07000

[ LogP ]:
2.13

[ 蒸汽压 ]:
0.5±0.3 mmHg at 25°C

[ 折射率 ]:
1.485

[ 储存条件 ]:
室温，密封

茴香酮MSDS

茴香酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RB7875200

CHEMICAL NAME :: 2-Norbornanone, 1,3,3-trimethyl-, (1R,4S)-(+)-

CAS REGISTRY NUMBER :: 4695-62-9

LAST UPDATED :: 199707

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C10-H16-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6160 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity)

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964

茴香酮安全信息

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
UN 1224 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
RB7875200

[ 包装等级 ]:
III

茴香酮合成路线

茴香酮上下游产品

茴香酮上游产品

茴香酮下游产品

茴香酮文献

[Chemical composition of essential oil obtained from Romanian fennel fruits].

Rev. Med. Chir. Soc. Med. Nat. Iasi. 115(2) , 590-4, (2011)

For therapeutical purposes, fennel (Foeniculum vulgare Mill.), an important aromatic plant, is used for its expectorant, antispasmodic, carminative and diuretic properties. The chemical composition, e...

Biosynthesis of monoterpenes: conversion of the acyclic precursors geranyl pyrophosphate and neryl pyrophosphate to the rearranged monoterpenes fenchol and fenchone by a soluble enzyme preparation from fennel (Foeniculum vulgare).

Arch. Biochem. Biophys. 200(2) , 524-33, (1980)

Kinetics and mechanisms of the tropospheric reactions of menthol, borneol, fenchol, camphor, and fenchone with hydroxyl radicals (OH) and chlorine atoms (Cl).

J. Phys. Chem. A 116(16) , 4097-107, (2012)

Relative kinetic techniques have been used to measure the rate coefficients for the reactions of oxygenated terpenes (menthol, borneol, fenchol, camphor, and fenchone) and cyclohexanol with hydroxyl r...

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茴香酮